Sandford Group Publications at Dartmouth

14. Hung, C.-T.; Wu, B.-S.; Chou, C.-T.; Sandford, C.*; Tsai, C.-C.* "Insight into Stereocontrol in the Asymmetric Intramolecular Allylation with a tert-Butylsulfinamide Nucleophile: Application in the Synthesis of Chiral Isoindoline-1-Carboxylic Acid Esters."

J. Org. Chem. 2023, 88, 613625.

Mentored Publications (prior to Dartmouth)

13. Tang, T.; Sandford, C.; Minteer, S. M.*; Sigman, M. S.* "Analyzing Mechanisms in Co(I) Redox Catalysis Using a Pattern Recognition Platform."

Chem. Sci. 2021, 12, 4771–4778.

12. Tsai, C.-C.§; Sandford, C.§; Wu, T.; Chen, B.; Sigman, M. S.*; Toste, F. D.* "Enantioselective Intramolecular Allylic Substitution via Synergistic Palladium/Chiral Phosphoric Acid Catalysis: Insight into Stereoinduction through Statistical Modeling."

Angew. Chem. Int. Ed. 2020, 59, 14647–14655.

[§ denotes equal contribution]

11. Barman, K.; Edwards, M. A.; Hickey, D. P.; Sandford, C.; Qiu, Y.; Gao, R.; Minteer, S. D.*; White, H. S.* "Electrochemical Reduction of [Ni(Mebpy)3]2+: Elucidation of the Redox Mechanism by Cyclic Voltammetry and Steady-State Voltammetry in Low Ionic Strength Solutions."

ChemElectroChem 2020, 7, 1473–1479.

10. Sandford, C.; Fries, L. R.; Ball, T. E.; Minteer, S. D.*; Sigman, M. S.* "Mechanistic Studies into the Oxidative Addition of Co(I) Complexes: Combining Electroanalytical Techniques with Parameterization."

J. Am. Chem. Soc. 2019, 141, 18877–18889.

[Highlighted as Editors' Choice in Science]

9. Sandford, C.; Edwards, M. A.; Klunder, K. J.; Hickey, D. P.; Li, M.; Barman, K.; Sigman, M. S.*; White, H. S.*; Minteer, S. D.* "A Synthetic Chemist's Guide to Electroanalytical Tools for Studying Reaction Mechanisms." [Review Article]

Chem. Sci. 2019, 10, 6404–6422.

[Themed collections: "Most popular 2019-2020 review articles", "Most popular 2019-2020 organic chemistry articles", and "Most popular 2018-2019 organic chemistry articles"]

8. Hickey, D. P.§; Sandford, C.§; Rhodes, Z.; Gensch, T.; Fries, L. R.; Sigman, M. S.*; Minteer, S. D.* "Investigating the Role of Ligand Electronics on Stabilizing Electrocatalytically Relevant Low-Valent Co(I) Intermediates."

J. Am. Chem. Soc. 2019, 141, 1382–1392.

[One of the top-20 most read articles in JACS in January 2019]

[§ denotes equal contribution]

7. García-Ruiz, C.; Chen, J. L.-Y.; Sandford, C.; Feeney, K.; Lorenzo, P.; Berionni, G.; Mayr, H.; Aggarwal, V. K.* "Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles."

J. Am. Chem. Soc. 2017, 139, 15324–15327.

[One of the top-20 most read articles in JACS in January 2017]

[Highlighted in ChemistryViews]

[Highlighted in Org. Process Res. Dev.]

6. Armstrong, R. J.; Sandford, C.; García-Ruiz, C.; Aggarwal, V. K.* "Conjunctive Functionalization of Vinyl Boronate Complexes with Electrophiles: A Diastereoselective Three-Component Coupling."

Chem. Commun. 2017, 53, 4922–4925.

5. Silvi, M.; Sandford, C.; Aggarwal, V. K.* "Merging Photoredox with 1,2-Metallate Rearrangements: The Photochemical Alkylation of Vinyl Boronate Complexes."

J. Am. Chem. Soc. 2017, 139, 5736–5739.

[Highlighted in Angew. Chem. Int. Ed.]

4. Sandford, C.; Aggarwal, V. K.* "Stereospecific Functionalizations and Transformations of Secondary and Tertiary Boronic Esters." [Review Article]

Chem. Commun. 2017, 53, 5481–5494.

[Themed collections: "Most cited articles from 2017", "Most cited Features from 2016, 2017", and "Most downloaded articles of 2017: Organic and Biological Chemistry"]

3. Wang, Y.; Noble, A.; Sandford, C.; Aggarwal, V. K.* "Enantiospecific Trifluoromethyl-Radical-Induced Three-Component Coupling of Boronic Esters with Furans."

Angew. Chem. Int. Ed. 2017, 56, 1810–1814.

[Highlighted in Org. Process Res. Dev.]

2. Farley, A. J. M.§; Sandford, C.§; Dixon, D. J.* "Bifunctional Iminophosphorane Catalyzed Enantioselective Sulfa-Michael Addition to Unactivated α-Substituted Acrylate Esters."

J. Am. Chem. Soc. 2015, 137, 15992–15995.

[§ denotes equal contribution]

1. Sandford, C.; Rasappan, R.; Aggarwal, V. K.* "Synthesis of Enantioenriched Alkylfluorides by the Fluorination of Boronate Complexes."

J. Am. Chem. Soc. 2015, 137, 10100–10103.

[One of the top-20 most read articles in JACS in August 2015]